Published July 4, 1985
| Version v1
Journal article
Ionic dissociation of hydroxycyclohexadienyl radical: effect on 13C hyperfine splittings
Description
The 13C hyperfine constants of 1,2,4,5-tetracarboxyhydroxycyclohexadienyl radical are shown to be substantially unaffected by ionization of the hydroxyl group. This result, which contrasts with the large decrease noted in a(H6), implies that the relatively low values for a(H6) observed in hydroxycyclohexadienyl radicals and their anions result not from distortion of the radical at the C6 site but rather from perturbation of the wave function at H6 by the OH or O- group. 4 references, 2 figures, 1 table
Additional details
Publishing Information
- Journal Title
- J. Phys. Chem.
- Journal Volume
- 89
- Journal Issue
- 14
- Series
- J. Phys. Chem.
- Journal Page Range
- 3101-3102
- ISSN
- 0022-3654
- CODEN
- JPCHA
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 17038745
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- CARBON 13; CARBOXYLIC ACIDS; COUPLING; DISSOCIATION; ELECTRON BEAMS; ELECTRON SPIN RESONANCE; EXPERIMENTAL DATA; FOURIER ANALYSIS; HYPERFINE STRUCTURE; RADICALS; RADIOLYSIS
- Descriptors DEC
- BEAMS; CARBON ISOTOPES; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; DATA; DECOMPOSITION; EVEN-ODD NUCLEI; INFORMATION; ISOTOPES; LEPTON BEAMS; LIGHT NUCLEI; MAGNETIC RESONANCE; NUCLEI; NUMERICAL DATA; ORGANIC ACIDS; ORGANIC COMPOUNDS; PARTICLE BEAMS; RADIATION EFFECTS; RESONANCE; STABLE ISOTOPES