Published August 1984
| Version v1
Journal article
CsCu2Cl3 and CsCu2Br3 by synproportionation at the metallic substrate
Description
CsCu2Cl3 and CsCu2Cl3 are obtained as single crystals via a dry route by synproportionation of mixtures of CsX/2 CuX (X = Cl, Br) and CsCuCl3, respectively, with the copper of the surface of a closed copper cylinder as the metallic substrate. Lattice constants of CsCu2Cl3 (CsCu2Br3) are: a = 950.75(9) (987.3(1)), b = 1189.8(2) (1235.5(2)), c = 559.92(6) (581.80(9)) pm, orthorhombic, Cmcm, Z = 4. Details of the Cs-X polyhedra (X = Cl, Br, I) and the double chains of tetrahedra [Cu2X3]- in CsCu2Cl3, CsCu2Br3, and CsCu2I3 are compared. (author)
Additional details
Additional titles
- Original title (German)
- Synproportionierung am metallischen Substrat: CsCu
Publishing Information
- Journal Title
- Z. Anorg. Allg. Chem.
- Journal Volume
- 515
- Series
- Z. Anorg. Allg. Chem.
- Journal Page Range
- 127-132
- ISSN
- 0044-2313
INIS
- Country of Publication
- Germany
- Country of Input or Organization
- German Democratic Republic
- INIS RN
- 16009457
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- CESIUM BROMIDES; CESIUM CHLORIDES; CHEMICAL PREPARATION; CHEMICAL REACTIONS; COPPER BROMIDES; COPPER CHLORIDES; EXPERIMENTAL DATA; INTERATOMIC DISTANCES; LATTICE PARAMETERS; MONOCRYSTALS; ORTHORHOMBIC LATTICES; SOLID SOLUTIONS; SPACE GROUPS; STRUCTURAL CHEMICAL ANALYSIS
- Descriptors DEC
- ALKALI METAL COMPOUNDS; BROMIDES; BROMINE COMPOUNDS; CESIUM COMPOUNDS; CHLORIDES; CHLORINE COMPOUNDS; COPPER COMPOUNDS; CRYSTAL LATTICES; CRYSTAL STRUCTURE; CRYSTALS; DATA; DISPERSIONS; DISTANCE; HALIDES; HALOGEN COMPOUNDS; HOMOGENEOUS MIXTURES; INFORMATION; MIXTURES; NUMERICAL DATA; SOLUTIONS; SYMMETRY GROUPS; SYNTHESIS; TRANSITION ELEMENT COMPOUNDS