Published January 1979
| Version v1
Journal article
On the mechanism of radical fragmentation of α-dioles and some of their derivatives
- 1. Belorusskij Gosudarstvennyj Univ., Minsk
Description
Studied is the composition of radiolysis products of deluted deaerated aqueous solutions of 1.2-dimethoxyethane and some of 1.3-dioxolanes. The solutions were leached (pH 12-13) to prevent hydrolysis of both initial and final products. Cs137 was used as a source of γ-radiation. Absorbed dose rate is equal to 4x1015 eV/mlxs. On the basis of the results obtained and literary data on radical fragmentation of α-dioles a possibility of ROCHCH2OR' particle decomposition according to the coordinated mechanism is discussed
Additional details
Additional titles
- Original title (Russian)
- К механизму фрагментации радикалов α-диолов и их некоторых производных
Publishing Information
- Journal Title
- Khim. Vys. Ehnerg.
- Journal Volume
- 13
- Journal Issue
- 1
- Series
- Khim. Vys. Ehnerg.
- Journal Page Range
- 19-22
- ISSN
- 0023-1193
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- USSR
- INIS RN
- 10468967
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- AQUEOUS SOLUTIONS; CHEMICAL REACTION KINETICS; DOSE RATES; GAMMA RADIATION; GLYCOLS; PH VALUE; RADICALS; RADIOLYSIS
- Descriptors DEC
- ALCOHOLS; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; DECOMPOSITION; DISPERSIONS; ELECTROMAGNETIC RADIATION; HOMOGENEOUS MIXTURES; HYDROXY COMPOUNDS; IONIZING RADIATIONS; KINETICS; MIXTURES; ORGANIC COMPOUNDS; RADIATION EFFECTS; RADIATIONS; REACTION KINETICS; SOLUTIONS
Optional Information
- Notes
- For English translation see the journal High Energy Chem.