Published 1998
| Version v1
Journal article
Crystal, molecular and electronic structure of [ReBr3(NO)(MeCN)(PPh3] complex
- 1. X-ray Crystallography Laboratory, Institute of General and Ecological Chemistry, Technical University of Lodz, Lodz (Poland)
- 2. Department of Inorganic and Radiation Chemistry, Institute of Chemistry, University of Silesia, Katowice (Poland)
Description
A new rhenium nitrosyl complex has been synthesized and characterized by IR, UV-vis, NMR (1H and 31P) and magnetochemical measurements. The crystal and molecular structure of [ReBr3(NO)(MeCN)(PPh3] has been determined by X-rays. The Re atom is of six-coordinate distorted octahedral configuration and linear nitrosyl ligand is trans towards the acetonitrile molecule. (author)
Additional details
Publishing Information
- Journal Title
- Polish Journal of Chemistry
- Journal Volume
- 72
- Journal Issue
- 3
- Journal Page Range
- p. 633-642
- ISSN
- 0137-5083
INIS
- Country of Publication
- Poland
- Country of Input or Organization
- Poland
- INIS RN
- 30008844
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
- Descriptors DEI
- ABSORPTION SPECTROSCOPY; CHEMICAL PREPARATION; CRYSTAL STRUCTURE; MAGNETIC PROPERTIES; MOLECULAR STRUCTURE; NITROSO COMPOUNDS; NUCLEAR MAGNETIC RESONANCE; PHOSPHINES; RHENIUM COMPLEXES; X-RAY DIFFRACTION
- Descriptors DEC
- COHERENT SCATTERING; COMPLEXES; DIFFRACTION; MAGNETIC RESONANCE; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; PHOSPHORUS COMPOUNDS; PHYSICAL PROPERTIES; RESONANCE; SCATTERING; SPECTROSCOPY; SYNTHESIS; TRANSITION ELEMENT COMPLEXES
Optional Information
- Contract/Grant/Project number
- KBN grant no. PB 1218/T09/97/12
- Notes
- 46 refs, 3 figs, 6 tabs