Published April 20, 2010 | Version v1
Journal article Metadata-only

Synthesis and thermal decomposition of [Bi6O4(OH)4](NH2SO3)6

Creators

  • 1. Department of Chemistry, Technical University, 8 St. Kliment Ohridski Blvd., 1000 Sofia (Bulgaria)
  • 2. Department of General and Inorganic Chemistry, University of Chemical Technology and Metallurgy, 8 St. Kliment Ohridski Blvd., 1756 Sofia (Bulgaria)
  • 3. Department of Organic Chemistry, University of Chemical Technology and Metallurgy, 8 St. Kliment Ohridski Blvd., 1756 Sofia (Bulgaria)

Description

The interaction of Bi(III) with aqueous solution of sulfamic acid is investigated, and a new compound with the following composition [Bi6O4(OH)4](NH2SO3)6 is derived. The substance obtained is characterized by various methods: elemental analysis, DTA, TG, FTIR and X-ray diffraction. Based on the experimental results, a mechanism of thermal decomposition of the newly synthesized compound is proposed.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.tca.2010.01.026

Additional details

Identifiers

DOI
10.1016/j.tca.2010.01.026;
PII
S0040-6031(10)00046-8;

Publishing Information

Journal Title
Thermochimica Acta
Journal Volume
502
Journal Issue
1-2
Journal Page Range
p. 90-93
ISSN
0040-6031
CODEN
THACAS

INIS

Country of Publication
Netherlands
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
44102653
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AQUEOUS SOLUTIONS; DIFFERENTIAL THERMAL ANALYSIS; INFRARED SPECTRA; INTERACTIONS; PYROLYSIS; SULFAMIC ACID; SYNTHESIS; X-RAY DIFFRACTION
Descriptors DEC
CHEMICAL REACTIONS; COHERENT SCATTERING; DECOMPOSITION; DIFFRACTION; DISPERSIONS; HOMOGENEOUS MIXTURES; HYDROGEN COMPOUNDS; INORGANIC ACIDS; INORGANIC COMPOUNDS; MIXTURES; SCATTERING; SOLUTIONS; SPECTRA; THERMAL ANALYSIS; THERMOCHEMICAL PROCESSES

Optional Information

Copyright
Copyright (c) 2010 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.