Published February 2000
| Version v1
Journal article
Electrochemical synthesis and properties of σ-fluoroacyl and σ-perfluoroalkyl transition metal complexes
- 1. RAN, Inst. Ehlementorganicheskikh Soedinenij im. A.N. Nesmeyanova, Moscow (Russian Federation)
Description
The electrochemical synthesis of σ-fluoracil complexes [M]-σ-CORf (M = C5H5(CO)3W or (CO)5Mn; Rf = CF3 or C4F9) was performed according to two procedures: 1) the electrochemical synthesis of [M]- from [M]2 followed by introduction of a fluorine-containing compound into the reaction; 2) the electrochemical synthesis of [M]- in the presence of a fluorine-containing compound. Trifluroacetic anhydride was demonstrated to be the best acylating agent. The electrochemical properties of the resulting complexes were studied
Abstract (Russian)
Осуществлен электрохимический синтез σ-фторацильных комплексов [M]-σ-CORf (M = C5H5(CO)3W или (CO)5Mn; Rf = CF3 или C4F9) в двух режимах: 1) предварительный электрохимический синтез [M]- из [M]2 с последующим введением в реакцию фторсодержащего соединения; 2) электрохимический синтез [M]- в присутствии фторсодержащего соединения. Наилучшим ацилирующим реагентом в этих реакциях является ангидрид трифторуксусной кислоты. Изучены электрохимические свойства полученных комплексовAdditional details
Additional titles
- Original title (Russian)
- Электрохимический синтез и свойства σ-фторацильных и σ-перфторалкильных комплексов переходных металлов
Publishing Information
- Journal Title
- Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya
- Journal Issue
- no.2
- Journal Page Range
- p. 373-375
- ISSN
- 0002-3353
- CODEN
- IASKA6
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- Russian Federation
- INIS RN
- 32002310
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CARBONYLS; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; CHEMICAL PROPERTIES; CHEMICAL REACTION YIELD; CYCLOPENTADIENE; ELECTROCHEMISTRY; ELECTROLYSIS; INFRARED SPECTRA; ORGANIC FLUORINE COMPOUNDS; TUNGSTEN COMPLEXES
- Descriptors DEC
- ALKENES; CHEMISTRY; COMPLEXES; CYCLOALKENES; DIENES; HYDROCARBONS; LYSIS; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; POLYENES; SPECTRA; SYNTHESIS; TRANSITION ELEMENT COMPLEXES; YIELDS
Optional Information
- Notes
- 5 refs., 1 fig., 1 tab.