Published June 1987 | Version v1
Journal article Metadata-only

Mathematical model of radiation solid-phase postpolymerization

Creators

  • 1. AN SSSR, Chernogolovka. Otdelenie Inst. Khimicheskoj Fiziki

Description

A mathematical model of radiation solid-phase postpolymerization, according to which at slow temperature variation of the thermostat and slow flow rate of both initial reagent and stabilized active centres the self-oscillating reaction conditions are possible that agree with the experimental data on radiation postpolymerization of crystal heptyl acrylate, γ-irradiated at 77 K. A method for determination of kinetic parameters under steady-state reaction conditions by comparing the experimental and theoretical results is proposed

Additional details

Additional titles

Original title (Russian)
Математическая модел' радиационной твердофазной постполимеризации

Publishing Information

Journal Title
Khim. Fiz.
Journal Volume
6
Journal Issue
6
Series
Khim. Fiz.
Journal Page Range
813-819
CODEN
KHFID

INIS

Country of Publication
USSR
Country of Input or Organization
USSR
INIS RN
19091777
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Descriptors DEI
ACRYLIC ACID ESTERS; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTION KINETICS; CRYSTALS; GAMMA RADIATION; LOW TEMPERATURE; MATHEMATICAL MODELS; POLYMERIZATION; RADIATION DOSES
Descriptors DEC
CARBOXYLIC ACID ESTERS; CHEMICAL REACTIONS; ELECTROMAGNETIC RADIATION; ESTERS; IONIZING RADIATIONS; KINETICS; ORGANIC COMPOUNDS; RADIATION EFFECTS; RADIATIONS; REACTION KINETICS