Published March 1979 | Version v1
Journal article Metadata-only

Reduction with trichlorosilane, 8

Creators

  • 1. Radiation Center of Osaka Prefecture, Sakai (Japan)

Description

Under γ irradiation, trichlorosilane was found to add to methyl methoxyacetate. Resulting adduct, CH3OCH2CH (OSiCl3) OCH3, was converted to 1-chloro- 1, 2-dimethoxyethane, CH3OCH2CHClOCH3, on warming with trichlorosilane. This chloride was further reduced to 1,2-dimethoxyethane with trichlorosilane under γ irradiation. These results support the three step mechanism (ester → adduct → α-chloro ether → ether) which we have presented for the reduction of esters with trichlorosilane. (author)

Additional details

Additional titles

Subtitle (English)
1, 2-dimethoxyethane from methyl methoxyacetate

Publishing Information

Journal Title
Annu. Rep. Radiat. Cent. Osaka Prefect.
Journal Volume
19
Series
Annu. Rep. Radiat. Cent. Osaka Prefect.
Journal Page Range
79-82
ISSN
0474-7879

INIS

Country of Publication
Japan
Country of Input or Organization
Japan
INIS RN
11516827
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Resource subtype / Literary indicator
Progress Report
Descriptors DEI
ALKANES; CARBOXYLIC ACID ESTERS; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTION KINETICS; ETHERS; GAMMA RADIATION; IRRADIATION; MIXTURES; NUCLEAR MAGNETIC RESONANCE; RADICALS; REDUCTION; SILICON CHLORIDES
Descriptors DEC
CHEMICAL REACTIONS; CHLORIDES; CHLORINE COMPOUNDS; DISPERSIONS; ELECTROMAGNETIC RADIATION; ESTERS; HALIDES; HALOGEN COMPOUNDS; HYDROCARBONS; IONIZING RADIATIONS; KINETICS; MAGNETIC RESONANCE; ORGANIC COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; RADIATION EFFECTS; RADIATIONS; REACTION KINETICS; RESONANCE; SILICON COMPOUNDS