Published 2008 | Version v1
Journal article Metadata-only

Oxidation reactions of derivatives of cis-octalins promoted by thallium trinitrate (TTN)

Creators

  • 1. Universidade de Sao Paulo (USP), SP (Brazil). Inst. de Quimica

Description

The reaction of ten cis-octalins and cis-octalones with thallium trinitrate (TTN) leads to different products, depending mainly on the substitution pattern of the substrate. Functionalized cis-hydrindanes were obtained from the reaction of 1,2,3,4,4a,5,8,8a-octahydro- 4a-methylnaphthalene and of 1,2,3,4,4a,5,8,8a-octahydro-4a,7-dimethylnaphthalene with TTN in acetonitrile, whereas a cyclic ether was formed treating 1,2,3,4,4a,5,8,8a-octahydro-6,8a-dimethylnaphthalene-1-ol with TTN in trimethylorthoformate (TMOF). (author)

Availability note (English)

Available from http://www.scielo.br/pdf/qn/v31n4/a14v31n4.pdf

Additional details

Additional titles

Original title (Portuguese)
Reacoes de oxidacao de cis-octalinas promovidas por trinitrato de talio (TTN)

Identifiers

URL
http://www.scielo.br/pdf/qn/v31n4/a14v31n4.pdf;

Publishing Information

Journal Title
Quimica Nova
Journal Volume
31
Journal Issue
4
Journal Page Range
p. 781-787
ISSN
0100-4042
CODEN
QUNODK

INIS

Country of Publication
Brazil
Country of Input or Organization
Brazil
INIS RN
39082682
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CARBON 13; DIELS-ALDER REACTION; FORMATES; GAS CHROMATOGRAPHY; GLYCOLS; HEXANE; HYDROGEN 1; INFRARED SPECTRA; LIQUID COLUMN CHROMATOGRAPHY; MASS SPECTRA; METHANOL; NAPHTHALENE; NMR SPECTRA; OXIDATION; SILICA GEL; SUBSTRATES; THALLIUM; THALLIUM NITRATES; ULTRAVIOLET SPECTRA
Descriptors DEC
ADSORBENTS; ALCOHOLS; ALKANES; AROMATICS; CARBON ISOTOPES; CARBOXYLIC ACID SALTS; CHEMICAL REACTIONS; CHROMATOGRAPHY; CONDENSED AROMATICS; ELEMENTS; EVEN-ODD NUCLEI; HYDROCARBONS; HYDROGEN ISOTOPES; HYDROXY COMPOUNDS; ISOTOPES; LIGHT NUCLEI; METALS; NITRATES; NITROGEN COMPOUNDS; NUCLEI; ODD-EVEN NUCLEI; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; SEPARATION PROCESSES; SPECTRA; STABLE ISOTOPES; THALLIUM COMPOUNDS

Optional Information

Notes
56 refs., 3 figs.