Published December 2018
| Version v1
Journal article
Rhodium Catalyst–Ionic Liquids Interaction by X-ray Photoelectron Spectroscopy Data
Creators
- 1. School of Material Science and Engineering Shenyang Ligong University (China)
- 2. School of Materials and Mechanical Engineering Beijing Technology and Business University (China)
Description
We investigate the Schrock–Osborn catalyst, [Rh(COD)(PPh3)2][PF6], in a series of ionic liquids by XPS. The electronic environment of the rhodium centre is demonstrated. The subtle change of the electronic environment of the rhodium centre due to the catalyst-ionic liquids interaction is revealed based upon Rh 3d binding energy. It suggests that the anion of ionic liquids can have significant impact on the electronic environment of the rhodium centre.
Additional details
Identifiers
Publishing Information
- Journal Title
- Russian Journal of Physical Chemistry
- Journal Volume
- 92
- Journal Issue
- 12
- Journal Page Range
- p. 2472-2475
- ISSN
- 0036-0244
- CODEN
- RJPCAR
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 51108928
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ANIONS; BINDING ENERGY; CATALYSTS; MOLTEN SALTS; RHODIUM; X-RAY PHOTOELECTRON SPECTROSCOPY
- Descriptors DEC
- CHARGED PARTICLES; ELECTRON SPECTROSCOPY; ELEMENTS; ENERGY; IONS; METALS; PHOTOELECTRON SPECTROSCOPY; PLATINUM METALS; REFRACTORY METALS; SALTS; SPECTROSCOPY; TRANSITION ELEMENTS
Optional Information
- Copyright
- Copyright (c) 2018 Pleiades Publishing, Ltd.