Published February 2003 | Version v1
Journal article Metadata-only

Reasons for different solubility of alkali metal chlorides in cadmium nitrate solutions

Creators

  • 1. Sankt-Peterburgskij Gosudarstvennyj Univ., Sankt-Peterburg (Russian Federation)

Description

Maximum solubility of MCl salts (M=Li, Na, K, Cs) in solutions of cadmium nitrate and perchlorate of different concentration was measured in detail for studying the reason for different solubility of alkali metal chlorides in aqueous solutions of cadmium nitrate with concentration of 0.9 and 4.1 mol/l. It is shown that in the framework of phenomenological model of the solutions concentrated solutions of salts forming several crystallohydrates can be considered as a system of mixed solvents. In this case, preferable interaction of LiCl and CsCl with the Cd(NO3)2·9H2O type solvent, while NaCl and KCl - with the Cd(NO3)2·4H2O type solvent can be mentioned

Abstract (Russian)

С целью изучения причины различной растворимости хлоридов щелочных металлов в водных растворах нитрата кадмия с концентрацией 0.9 и 4.1 моль/л детально измерена максимальная растворимость солей MCl (M=Li, Na, K, Cs) в растворах нитрата и перхлората кадмия различных концентраций. Показано, что в рамках феноменологической модели растворов концентрированные растворы солей, образующих несколько кристаллогидратов, можно рассматривать как систему смешанных растворителей. В этом случае можно говорить о предпочтительном взаимодействии LiCl и CsCl с растворителем типа Cd(NO3)2·9H2O, а NaCl и KCl - с Cd(NO3)2·4H2O

Additional details

Additional titles

Original title (Russian)
Причина разной растворимости хлоридов щелочных металлов в растворе нитрата кадмия

Publishing Information

Journal Title
Zhurnal Obshchej Khimii
Journal Volume
73
Journal Issue
2
Journal Page Range
p. 177-181
ISSN
0044-460X
CODEN
ZOKHA4

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
37011352
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ALKALI METAL COMPOUNDS; AQUEOUS SOLUTIONS; CADMIUM COMPLEXES; CADMIUM NITRATES; CADMIUM PERCHLORATES; CHEMICAL COMPOSITION; CHLORIDES; CONCENTRATION RATIO; HYDRATES; SOLUBILITY; SOLVENTS
Descriptors DEC
CADMIUM COMPOUNDS; CHLORINE COMPOUNDS; COMPLEXES; DIMENSIONLESS NUMBERS; DISPERSIONS; HALIDES; HALOGEN COMPOUNDS; HOMOGENEOUS MIXTURES; MIXTURES; NITRATES; NITROGEN COMPOUNDS; OXYGEN COMPOUNDS; PERCHLORATES; SOLUTIONS

Optional Information

Notes
5 refs., 1 fig.