Published August 2007
| Version v1
Journal article
Radiolysis of ferrocyanide solutions studied by infrared spectroscopy
- 1. CEA/Saclay, DSM/DRECAM/SCM/URA 331 CNRS, F-91191Gif-sur-Yvette Cedex (France)
Description
The behavior of the neutral and basic aqueous ferrocyanide system under irradiation is investigated using the coupling of a LINAC with infrared spectroscopy. The comparison between the neutral and basic system evidences the formation of the hydroxopentacyanoferrate (III) ions and gives information on the reaction mechanisms. The pseudo-protective effect of the dissolved dioxygen on the ferrocyanide is explained via a mechanism implying the superoxide radical anion
Additional details
Identifiers
- DOI
- 10.1016/j.radphyschem.2007.02.019;
- PII
- S0969-806X(07)00052-7;
Publishing Information
- Journal Title
- Radiation Physics and Chemistry (1993)
- Journal Volume
- 76
- Journal Issue
- 8-9
- Journal Page Range
- p. 1280-1284
- ISSN
- 0969-806X
- CODEN
- RPCHDM
Conference
- Title
- 11. Tihany symposium on radiation chemistry
- Dates
- 26-31 Aug 2006
- Place
- Eger (Hungary)
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 38103996
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Resource subtype / Literary indicator
- Conference
- Descriptors DEI
- ABSORPTION SPECTROSCOPY; FERROCYANIDES; FOURIER TRANSFORMATION; INFRARED SPECTRA; LINEAR ACCELERATORS; RADIOLYSIS; REACTION KINETICS; SUPEROXIDE RADICALS
- Descriptors DEC
- ACCELERATORS; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; COMPLEXES; DECOMPOSITION; INTEGRAL TRANSFORMATIONS; IRON COMPLEXES; KINETICS; RADIATION EFFECTS; RADICALS; SPECTRA; SPECTROSCOPY; TRANSFORMATIONS; TRANSITION ELEMENT COMPLEXES
Optional Information
- Copyright
- Copyright (c) 2007 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.