Published August 28, 2015 | Version v1
Journal article

From statistics of regular tree-like graphs to distribution function and gyration radius of branched polymers

  • 1. Physico-Chimie Curie UMR 168, Institut Curie, PSL Research University, 26 rue d'Ulm, F-75248 Paris Cedex 05 (France)
  • 2. Université Paris—Sud/CNRS, LPTMS, UMR8626, Bât. 100, F-91405 Orsay (France)

Description

We consider flexible branched polymer, with quenched branch structure, and show that its conformational entropy as a function of its gyration radius R, at large R, obeys, in the scaling sense, Δ S R 2 / ( a 2 L ), with a bond length (or Kuhn segment) and L defined as an average spanning distance. We show that this estimate is valid up to at most the logarithmic correction for any tree. We do so by explicitly computing the largest eigenvalues of Kramers matrices for both regular and 'sparse' three-branched trees, uncovering on the way their peculiar mathematical properties. (paper)

Availability note (English)

Available from http://dx.doi.org/10.1088/1751-8113/48/34/345003

Additional details

Publishing Information

Journal Title
Journal of Physics. A, Mathematical and Theoretical (Online)
Journal Volume
48
Journal Issue
34
Journal Page Range
[11 p.]
ISSN
1751-8121

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
51040539
Subject category
S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS;
Descriptors DEI
BOND LENGTHS; DISTRIBUTION FUNCTIONS; EIGENVALUES; ENTROPY; GRAPH THEORY; MATRICES; POLYMERS; STATISTICS
Descriptors DEC
DIMENSIONS; FUNCTIONS; LENGTH; MATHEMATICS; PHYSICAL PROPERTIES; THERMODYNAMIC PROPERTIES