Published August 28, 2015
| Version v1
Journal article
From statistics of regular tree-like graphs to distribution function and gyration radius of branched polymers
Creators
- 1. Physico-Chimie Curie UMR 168, Institut Curie, PSL Research University, 26 rue d'Ulm, F-75248 Paris Cedex 05 (France)
- 2. Université Paris—Sud/CNRS, LPTMS, UMR8626, Bât. 100, F-91405 Orsay (France)
Description
We consider flexible branched polymer, with quenched branch structure, and show that its conformational entropy as a function of its gyration radius R, at large R, obeys, in the scaling sense, , with a bond length (or Kuhn segment) and L defined as an average spanning distance. We show that this estimate is valid up to at most the logarithmic correction for any tree. We do so by explicitly computing the largest eigenvalues of Kramers matrices for both regular and 'sparse' three-branched trees, uncovering on the way their peculiar mathematical properties. (paper)
Availability note (English)
Available from http://dx.doi.org/10.1088/1751-8113/48/34/345003Additional details
Identifiers
Publishing Information
- Journal Title
- Journal of Physics. A, Mathematical and Theoretical (Online)
- Journal Volume
- 48
- Journal Issue
- 34
- Journal Page Range
- [11 p.]
- ISSN
- 1751-8121
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 51040539
- Subject category
- S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS;
- Descriptors DEI
- BOND LENGTHS; DISTRIBUTION FUNCTIONS; EIGENVALUES; ENTROPY; GRAPH THEORY; MATRICES; POLYMERS; STATISTICS
- Descriptors DEC
- DIMENSIONS; FUNCTIONS; LENGTH; MATHEMATICS; PHYSICAL PROPERTIES; THERMODYNAMIC PROPERTIES