Published March 1977
| Version v1
Journal article
Chemical models of chains electron transfer in hydroxylating ferment systems
Creators
- 1. AN Belorusskoj SSR, Minsk. Inst. Bioorganicheskoj Khimii
Description
The rate constants are measured of consumption of nicotineamidedinucleotide (NAD-N) during its oxidation by molecular oxygen with the participation of Ti4+, Sn4+, Cu2+, Fe3+, VO2+, and Ce4+ ions in mixtures of acetonitrile with water and of dioxane with water taken in a volume ratio of 1:1 (46 deg C). The kinetics of oxidation of NAD-N with the participation of Ti4+ at 37 deg C in a water-acetonitrile medium is studied in detail. The hydroxylating capacity of the system NAD-N - Ti4+ - O2 with respect to naphthalene is proved. The reaction mechanism and its relationship with the microsomal chains of electron transport are discussed
Additional details
Additional titles
- Original title (Russian)
- Химические модели цепей переноса электронов в гидроксилирующих ферментных системах
Publishing Information
- Journal Title
- Kinet. Katal.
- Journal Volume
- 18
- Journal Issue
- 2
- Series
- Kinet. Katal.
- Journal Page Range
- 394-398
INIS
- Country of Publication
- USSR
- Country of Input or Organization
- USSR
- INIS RN
- 9378193
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CATALYSTS; CATIONS; CERIUM COMPOUNDS; CHEMICAL REACTION KINETICS; ENZYMES; MIXED SOLVENTS; NUCLEOTIDES; OXIDATION; VANADIUM COMPOUNDS
- Descriptors DEC
- CHARGED PARTICLES; CHEMICAL REACTIONS; DISPERSIONS; IONS; KINETICS; MIXTURES; ORGANIC COMPOUNDS; RARE EARTH COMPOUNDS; REACTION KINETICS; SOLVENTS; TRANSITION ELEMENT COMPOUNDS
Optional Information
- Notes
- For English translation see the journal Kinet. Catal.