Published 1994
| Version v1
Book
Pulse radiolysis of 2-mercapto benzimidazole in aqueous solutions
Creators
- 1. Bhabha Atomic Research Centre, Bombay (India). Applied Chemistry Division
Description
The initial eaq-/H adducts of 2-mercapto benzimidazole(MBZ) (λmax ∼ 370 nm) which are mild reductants react with parent compound to give an intermolecular 3-electron bonded species with λmax at 590 nm. The rate constants for the reactions of MBZ with eaq- and OH radicals at pH 7 and with H-atoms at pH 2 were determined. OH radical reaction with MBZ gives an intramolecular 3-electron bonded species. (author). 2 refs., 2 figs., 1 tab
Additional details
Publishing Information
- Publisher
- Bhabha Atomic Research Centre.
- Imprint Place
- Bombay (India)
- Imprint Title
- Trombay symposium on radiation and photochemistry. Preprints vol.2: contributed papers
- Imprint Pagination
- 407 p.
- Journal Page Range
- p. 40-42.
Conference
- Title
- Trombay symposium on radiation and photochemistry.
- Acronym
- TSRP-94
- Dates
- 17-21 Jan 1994.
- Place
- Bombay (India).
INIS
- Country of Publication
- India
- Country of Input or Organization
- India
- INIS RN
- 26062494
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Resource subtype / Literary indicator
- Conference
- Descriptors DEI
- ABSORPTION SPECTRA; AQUEOUS SOLUTIONS; BENZIMIDAZOLES; CHEMICAL REACTION KINETICS; HYDROXYL RADICALS; MOLECULAR STRUCTURE; ORGANIC SULFUR COMPOUNDS; OXIDATION; PH VALUE; PULSED IRRADIATION; RADIOLYSIS; REDUCTION; SOLVATED ELECTRONS
- Descriptors DEC
- AZOLES; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; DECOMPOSITION; DISPERSIONS; ELECTRONS; ELEMENTARY PARTICLES; FERMIONS; HETEROCYCLIC COMPOUNDS; HOMOGENEOUS MIXTURES; IMIDAZOLES; IRRADIATION; KINETICS; LEPTONS; MIXTURES; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; RADIATION EFFECTS; RADICALS; REACTION KINETICS; SOLUTIONS; SPECTRA