Published 1990
| Version v1
Journal article
Disproportionation of alkoxy radicals in irradiated monocrystals of polyhydroxycompounds
Description
Using ESR method kinetics in disproportionation of alkoxy radicals in irradiated at 77K monocrystals of ribitol, β-methyl-D-galactopyranoside and their deuterated analogues is studied. Hydrogen bonds effect on the ratio of probabilities of disproportionation reactions of alkoxy radicals and their transition into hydroxy-alkyl radicals is discussed
Additional details
Additional titles
- Original title (Russian)
- Диспропорционирование алкоксильных радикалов в облученных монокристаллах полиоксисоединений
Publishing Information
- Journal Title
- Khimicheskaya Fizika
- Journal Volume
- 9
- Journal Issue
- 5
- Series
- Khim. Fiz.
- Journal Page Range
- 623-627
- ISSN
- 0207-401X
- CODEN
- KHFID
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- USSR
- INIS RN
- 22033538
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- ACTIVATION ENERGY; ALKOXY RADICALS; CHEMICAL BONDS; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTION KINETICS; G VALUE; LOW TEMPERATURE; MONOCRYSTALS; OXIDATION; RADIATION DOSES; REACTION INTERMEDIATES; REDUCTION; SACCHARIDES
- Descriptors DEC
- CARBOHYDRATES; CHEMICAL REACTIONS; CRYSTALS; ENERGY; KINETICS; ORGANIC COMPOUNDS; RADIATION EFFECTS; RADICALS; REACTION KINETICS