Published February 2021 | Version v1
Journal article Metadata-only

A cocrystallization of polyoxotitanium cages with lanthanide clusters

Creators

  • 1. Department of Chemistry, University of Cambridge, CB2 1EW (United Kingdom)
  • 2. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002 (China)
  • 3. Shanghai Normal University, Shanghai Key Laboratory of Rare Earth Functional Materials, Shanghai, 200234 (China)
  • 4. College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou, 310014 (China)

Description

Highlights: • Present here is a new structure type of lanthanide doped polyoxotitanium (Ln-POT). • A cocrystallization of polyoxotitanium cages with lanthanide clusters is observed. • The temperature has a great influence on the structure type of Ln-POT. Present herein is a new structure type of lanthanide-doped polyoxotitanium (Ln-POT) involving the separation of the polyoxotitanium and lanthanide clusters. A unique cocrystallization is observed in the structure of H6[Ti12(OiPr)18(μ3-O14)][La3(NO3)11(OiPr)6] (1). Diffuse reflectance spectroscopy showing lanthanide doping is shown to give favorable light absorption properties.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.jssc.2020.121852

Additional details

Identifiers

DOI
10.1016/j.jssc.2020.121852;
PII
S0022459620306836;

Publishing Information

Journal Title
Journal of Solid State Chemistry (Print)
Journal Volume
294
Journal Page Range
vp.
ISSN
0022-4596
CODEN
JSSCBI

INIS

Country of Publication
Netherlands
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
54024507
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ABSORPTION; DOPED MATERIALS; NITRATES; RARE EARTHS; SPECTROSCOPY
Descriptors DEC
ELEMENTS; MATERIALS; METALS; NITROGEN COMPOUNDS; OXYGEN COMPOUNDS; SORPTION

Optional Information

Copyright
Copyright (c) 2020 Published by Elsevier Inc. All rights reserved.