Volumetric properties of dilute (d-glucose + H2O) solutions at temperatures from (293.15 to 433.15) K and pressures from (0.10 to 50.00) MPa
- 1. Department of Earth & Environmental Sciences, California State University, East Bay, 25800 Carlos Bee Blvd., Hayward, CA 94542 (United States)
- 2. Department of Geological Sciences, 101 Geology Building, University of Missouri, Columbia, MO 65211 (United States)
Description
Highlights: • These data significantly extend the experimental database for aqueous solutions of d-glucose. • Partial molar volume at infinite dilution is sensitive to temperature in the range examined. • Partial molar volume at infinite dilution is insensitive to pressure in the range examined. -- Abstract: The densities of aqueous solutions of d-glucose were measured at temperatures from (293.15 to 433.15) K and pressures from (0.10 to 50.00) MPa using a vibrating-tube densimeter. Apparent molar volumes Vφ,m and partial molar volumes at infinite dilution V∞ were calculated from the experimental results. V∞ increases as temperature increases and varies linearly with temperature above ∼300 K. In addition, V∞ does not vary as a function of pressure up to 50.0 MPa. Comparison of these results with previous studies indicate excellent agreement and significantly extend the experimental database for aqueous solutions of d-glucose to elevated temperatures and pressures.
Additional details
Identifiers
- DOI
- 10.1016/j.jct.2018.08.020;
- PII
- S0021961418301812;
Publishing Information
- Journal Title
- Journal of Chemical Thermodynamics
- Journal Volume
- 128
- Journal Page Range
- p. 372-382
- ISSN
- 0021-9614
- CODEN
- JCTDAF
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 55048130
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- APPARENT MOLAL VOLUME; AQUEOUS SOLUTIONS; DENSIMETERS; DILUTION; GLUCOSE; PARTIAL MOLAL VOLUME; PRESSURE DEPENDENCE
- Descriptors DEC
- ALDEHYDES; CARBOHYDRATES; DISPERSIONS; HEXOSES; HOMOGENEOUS MIXTURES; MEASURING INSTRUMENTS; MIXTURES; MONOSACCHARIDES; ORGANIC COMPOUNDS; SACCHARIDES; SOLUTIONS
Optional Information
- Copyright
- Copyright (c) 2018 Elsevier Ltd.