Published January 2019 | Version v1
Journal article

Volumetric properties of dilute (d-glucose + H2O) solutions at temperatures from (293.15 to 433.15) K and pressures from (0.10 to 50.00) MPa

  • 1. Department of Earth & Environmental Sciences, California State University, East Bay, 25800 Carlos Bee Blvd., Hayward, CA 94542 (United States)
  • 2. Department of Geological Sciences, 101 Geology Building, University of Missouri, Columbia, MO 65211 (United States)

Description

Highlights: • These data significantly extend the experimental database for aqueous solutions of d-glucose. • Partial molar volume at infinite dilution is sensitive to temperature in the range examined. • Partial molar volume at infinite dilution is insensitive to pressure in the range examined. -- Abstract: The densities of aqueous solutions of d-glucose were measured at temperatures from (293.15 to 433.15) K and pressures from (0.10 to 50.00) MPa using a vibrating-tube densimeter. Apparent molar volumes Vφ,m and partial molar volumes at infinite dilution V were calculated from the experimental results. V increases as temperature increases and varies linearly with temperature above ∼300 K. In addition, V does not vary as a function of pressure up to 50.0 MPa. Comparison of these results with previous studies indicate excellent agreement and significantly extend the experimental database for aqueous solutions of d-glucose to elevated temperatures and pressures.

Additional details

Identifiers

DOI
10.1016/j.jct.2018.08.020;
PII
S0021961418301812;

Publishing Information

Journal Title
Journal of Chemical Thermodynamics
Journal Volume
128
Journal Page Range
p. 372-382
ISSN
0021-9614
CODEN
JCTDAF

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
55048130
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
APPARENT MOLAL VOLUME; AQUEOUS SOLUTIONS; DENSIMETERS; DILUTION; GLUCOSE; PARTIAL MOLAL VOLUME; PRESSURE DEPENDENCE
Descriptors DEC
ALDEHYDES; CARBOHYDRATES; DISPERSIONS; HEXOSES; HOMOGENEOUS MIXTURES; MEASURING INSTRUMENTS; MIXTURES; MONOSACCHARIDES; ORGANIC COMPOUNDS; SACCHARIDES; SOLUTIONS

Optional Information

Copyright
Copyright (c) 2018 Elsevier Ltd.