Published April 1993
| Version v1
Journal article
Template synthesis of oxozirconium(IV) complexes with tetraaza 16- and 18-membered macrocyclic ligands
Creators
- 1. North Eastern Regional Institute of Science and Technology, Itanagar (India). Chemistry Division
Description
The macrocyclic complexes of types [ZrO(mac)H2O]Cl2 or [Zr(OH)2(mac)]Cl2 (where mac = macrocyclic ligands derived by condensation of diamines with β-diketones) have been synthesized by an in situ method where the metal cation acts as a template. The isolated complexes have been characterized on the basis of elemental analyses, electrical conductance and infrared spectral data. The oxozirconium(IV) complexes are six-coordinate. The tetraaza macrocyclic ligands are coordinated to the metal ion through four azomethine nitrogen atoms. (author). 14 refs., 1 tab
Additional details
Publishing Information
- Journal Title
- Asian Journal of Chemistry
- Journal Volume
- 5
- Journal Issue
- 2
- Journal Page Range
- p. 335-339.
- ISSN
- 0970-7077
- CODEN
- AJCHEW
INIS
- Country of Publication
- India
- Country of Input or Organization
- India
- INIS RN
- 24071456
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- AQUEOUS SOLUTIONS; CATIONS; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; COLOR; DECOMPOSITION; ETHANOL; LIGANDS; ORGANIC NITROGEN COMPOUNDS; STRUCTURAL CHEMICAL ANALYSIS; VIBRATIONAL STATES; ZIRCONIUM COMPLEXES; ZIRCONIUM COMPOUNDS
- Descriptors DEC
- ALCOHOLS; CHARGED PARTICLES; CHEMICAL REACTIONS; COMPLEXES; DISPERSIONS; ENERGY LEVELS; EXCITED STATES; HOMOGENEOUS MIXTURES; HYDROXY COMPOUNDS; IONS; MIXTURES; OPTICAL PROPERTIES; ORGANIC COMPOUNDS; ORGANOLEPTIC PROPERTIES; PHYSICAL PROPERTIES; SOLUTIONS; SYNTHESIS; TRANSITION ELEMENT COMPLEXES; TRANSITION ELEMENT COMPOUNDS