Analysis of the binary mixtures using the reaction between iron(II) and cerium(IV) sulphate in phosphoric acid medium

The reaction between iron(II) and cerium(IV) sulphate in phosphoric acid medium (6-12M) is studied potentiometrically and visually using methylene blue, thionine, azure A, azure B, azure C, toluidine blue, new methylene blue, variamine blue, ferroin, p-ethoxychrysoidine, N-phenylanthranilic acid and barium diphenylamine sulphonate as indicators. This reaction is made use for the analysis of binary mixtures of Fe(II)-Sn(II), Fe(II)-Ti(III), Fe(II)-U(IV), Fe(II)-Mo(V), Fe(II)-Fe(III) with Ce(IV) sulphate and Ce(IV)-U(VI), Ce(IV)-Mo(VI), Ce(IV)-V(V) and Ce(IV)-Cu(II) with iron (II). (author)