Published September 2005 | Version v1
Journal article

Relativistic multireference many-body perturbation calculations on multi-valence-electron systems: Benchmarks on Zn-like ions

  • 1. Department of Chemistry, University of Puerto Rico, P.O. Box 23346, San Juan, 00931-3346 (Puerto Rico)

Description

High-accuracy calculations of term energies and wavelengths of resonance lines in Zn-like ions have been performed as benchmarks in the quest for accurate theoretical treatments of relativity, electron correlation, and quantum electrodynamic effects in multivalence-electron systems. Computed wavelengths of the 4s21S0-4s4p 1P1o transitions are compared with the recent high-resolution wavelength measurements using electron-beam ion traps [E. Traebert, P. Beiersdorfer, and H. Chen, Phys. Rev. A 70, 032506 (2004)], a sensitive means of testing electronic structure theory that has revealed the inadequacies in treating multiple valence electrons in the extant relativistic many-body calculations

Additional details

Identifiers

Publishing Information

Journal Title
Physical Review. A
Journal Volume
72
Journal Issue
3
Journal Page Range
p. 032512-032512.10
ISSN
1050-2947
CODEN
PLRAAN

Optional Information

Notes
(c) 2005 The American Physical Society