Published September 1980 | Version v1
Journal article Metadata-only

Reaction of N-bromosuccinimide with mono-and binuclear zirconium and hafnium chelate cyclopentadienyl complexes

Creators

  • 1. AN SSSR, Moscow. Inst. Ehlementoorganicheskikh Soedinenij

Description

The reaction of CpHf (C5H7O2)2 Cl, CpZr(C5H7O2)2(C15H11O2) and [CpZr(C5H7O2)2]2O chelate cyclopentadienyl complexes with N-bromosuccinimide brings about bromination only in chelate cycles with the retention of all ligands in molecules. CpZr(C15H11O2)2Cl bromination with N-bromosuccinimide proceeds in dibenzoylmethanate rings; chlorine exchange for bromine takes place at the same time. N-bromosuccinimide effect on (C5H7O2)4Zr in equimolar ratios brings about the formation of (C5H7O2)3Zr(C5H6O2Br)

Additional details

Additional titles

Original title (Russian)
Взаимодействие Н-бромсукцинимида с моно-и биядерными хелатными циклопентадиенильными комплексами циркония и гафния

Publishing Information

Journal Title
Izv. Akad. Nauk SSSR, Ser. Khim.
Journal Issue
no.9
Series
Izv. Akad. Nauk SSSR, Ser. Khim.
ISSN
0002-3353

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
12594785
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
BROMINATION; CHELATES; CHEMICAL REACTION KINETICS; CHEMICAL REACTION YIELD; CYCLOALKENES; DIENES; HAFNIUM COMPLEXES; IMIDES; INFRARED SPECTRA; NMR SPECTRA; ORGANIC BROMINE COMPOUNDS; ZIRCONIUM COMPLEXES
Descriptors DEC
ALKENES; CHEMICAL REACTIONS; COMPLEXES; HALOGENATION; HYDROCARBONS; KINETICS; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; POLYENES; REACTION KINETICS; SPECTRA; TRANSITION ELEMENT COMPLEXES

Optional Information

Notes
For English translation see the journal Bulletin of the Academy of Sciences USSR, Division of Chemical Science (USA).