Published November 21, 1992
| Version v1
Journal article
Infrared and Raman spectroscopic studies on the H-D equilibrium isotope effect in the electron-transfer equilibrium of thianthrene and its radical cation
- 1. Lanzhou Univ., GS (China). National Lab. of Applied Organic Chemistry
- 2. Lanzhou Univ., GS (China). Dept. of Chemsitry
Description
Infrared and resonance Raman spectra of thianthrene (Th), perdeuteriated thianthrene ([2H8]Th) and their radical cation perchlorates (Thradical +ClO4- respectively have been measured. Comparison of the frequency shifts caused by the perdeuteriation and the radical cation formation of thianthrene enables evaluation of the free energy change of 137 cal mol-1 for the electron-exchange equilibrium Th + [2H8]Th.+ ↔ Th+ + [2H8]Th. (Author)
Additional details
Publishing Information
- Journal Title
- Journal of the Chemical Society. Faraday Transactions
- Journal Volume
- 88
- Journal Issue
- 22
- Journal Page Range
- p. 3323-3326.
- ISSN
- 0956-5000
- CODEN
- JCFTEV
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- United Kingdom
- INIS RN
- 24031933
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- AROMATICS; CATIONS; DEUTERATION; DEUTERIUM; ELECTRON TRANSFER; FREE ENERGY; HYDROGEN; INFRARED SPECTRA; ISOTOPE EFFECTS; ORGANIC SULFUR COMPOUNDS; PERCHLORATES; RAMAN SPECTRA
- Descriptors DEC
- CHARGED PARTICLES; CHEMICAL REACTIONS; CHLORINE COMPOUNDS; ELEMENTS; ENERGY; HALOGEN COMPOUNDS; HYDROGEN ISOTOPES; IONS; ISOTOPES; LIGHT NUCLEI; NONMETALS; NUCLEI; ODD-ODD NUCLEI; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; SPECTRA; STABLE ISOTOPES; THERMODYNAMIC PROPERTIES