Published February 1989 | Version v1
Journal article Metadata-only

Complexes of manganese borohydrides with borohydrides of organic cations

Creators

  • 1. AN SSSR, Chernogolovka (USSR). Inst. Novykh Khimicheskikh Problem

Description

Methods of IR-spectroscopy and complex thermal analysis were used to investigate and characterize (Bu4N)(Mn(BH4)3), (Ph4P)(Mn(BH4)3), (Ph4P)(Mn(BH4)3(THF)), (Ph4P)(Mn(BH4)2Cl), (Ph4P)(Mn(BH4)2Cl(THF)) compounds, prepared by Mn(BH4)2(THF)3 interaction with borohydrides of tetrabutylammonium, tetraphenylphosphonium and tetraphenylphosphonium chloride. Crystal and molecular structure of (Ph4P)(Mn(BH4)3-xClx(THF)) (x ∼ 0.5) manganese complex

Additional details

Additional titles

Original title (Russian)
Комплексные соединения моргидрида марганца с боргидридами органических катионов

Publishing Information

Journal Title
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya
Journal Issue
no.2
Series
Izv. Akad. Nauk SSSR, Ser. Khim.
ISSN
0002-3353
CODEN
IASKA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
20063052
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
BOROHYDRIDES; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; CHEMICAL REACTION YIELD; CHLORIDES; CRYSTAL LATTICES; INFRARED SPECTRA; LATTICE PARAMETERS; MANGANESE COMPLEXES; MOLECULAR STRUCTURE; ORGANIC PHOSPHORUS COMPOUNDS; ORGANIC SOLVENTS; PYROLYSIS; QUATERNARY COMPOUNDS
Descriptors DEC
AMINES; BORON COMPOUNDS; CHEMICAL REACTIONS; CHLORINE COMPOUNDS; COMPLEXES; CRYSTAL STRUCTURE; DECOMPOSITION; HALIDES; HALOGEN COMPOUNDS; HYDROGEN COMPOUNDS; NONAQUEOUS SOLVENTS; ORGANIC COMPOUNDS; SOLVENTS; SPECTRA; SYNTHESIS; TRANSITION ELEMENT COMPLEXES