Published August 15, 1982
| Version v1
Journal article
Mercury-199 nuclear magnetic resonance relaxation in some mercury(II) compounds
- 1. Winnipeg Univ., Manitoba (Canada). Dept. of Chemistry
- 2. Guelph Univ., Ontario (Canada). Dept. of Chemistry
- 3. Bruker Spectrospin, Mississauga, Ontario (Canada)
Description
Mercury-199 spin-lattice relaxation times are reported for several mercury(II) compounds at 5.875 and 9.40 T. From the field dependence of T1 in Hg(CN)2, Hg(CH3)2, and Hg(C6H5)2, 199Hg chemical shielding anisotropies of 3800, 5820, and 5800 ppm are calculated. The errors in these of estimates of δσ are at least 10%. Some implications of the large δσ(199Hg) values in high field nmr studies are discussed
Additional details
Publishing Information
- Journal Title
- Can. J. Chem.
- Journal Volume
- 60
- Journal Issue
- 16
- Series
- Can. J. Chem.
- Journal Page Range
- 2113-2117
- ISSN
- 0008-4042
INIS
- Country of Publication
- Canada
- Country of Input or Organization
- Canada
- INIS RN
- 14759485
- Subject category
- S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
- Descriptors DEI
- CYANIDES; MERCURY COMPOUNDS; MERCURY 199; NUCLEAR MAGNETIC RESONANCE; ORGANIC MERCURY COMPOUNDS; SPIN-LATTICE RELAXATION
- Descriptors DEC
- EVEN-ODD NUCLEI; HEAVY NUCLEI; INTERNAL CONVERSION RADIOISOTO; ISOMERIC TRANSITION ISOTOPES; ISOTOPES; MAGNETIC RESONANCE; MERCURY ISOTOPES; MINUTES LIVING RADIOISOTOPES; NUCLEI; ORGANIC COMPOUNDS; RADIOISOTOPES; RELAXATION; RESONANCE; STABLE ISOTOPES
Optional Information
- Notes
- 27 refs.