Published May 1994 | Version v1
Journal article Metadata-only

Radiolysis mechanism for perfluoroisobutylene

Creators

  • 1. Halogen Ural Production Association (Russian Federation)
  • 2. Institute of Chemical Physics, Chernogolovka (Russian Federation)

Description

The radical yield from the radiolysis of crystalline perfluoroisobutylene, G(R) ≅ 8.6, is much larger than for linear perfluoro hydrocarbons. The main gaseous product from radiolysis of perfluoroisobutylene is tetrafluoroethylene G(C2F4) = 2, and perfluoroisobutane G(C4F10) = 1.8. Perfluoromethane G(CF4) ≅ 0.2 and hexafluoropropylene G(C3F6) ≅ 0.2 were also formed

Additional details

Publishing Information

Journal Title
High Energy Chemistry
Journal Volume
27
Journal Issue
6
Journal Page Range
p. 428-431.
ISSN
0018-1439
CODEN
HIECAP

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
26032433
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Resource subtype / Literary indicator
Translation
Descriptors DEI
CHEMICAL REACTION YIELD; ORGANIC FLUORINE COMPOUNDS; RADICALS; RADIOLYSIS
Descriptors DEC
CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; DECOMPOSITION; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; RADIATION EFFECTS; YIELDS

Optional Information

Notes
Cover-to-cover Translation of Khimiya Vysokikh Energij (USSR); Translated from Khimiya Vysokikh Energij; 27: No. 6, 27-30(Nov-Dec 1993).