Published September 1994
| Version v1
Journal article
Synthesis of tris(β-diketonato)indium from metallic indium and bis(β-diketonato)copper
- 1. Science Univ. of Tokyo (Japan). Faculty of Engineering
Description
The reaction between metallic indium and bis(β-diketonato)copper(II) in non-aqueous solution produced the corresponding indium chelate compounds of the type [In(dik)3], where Hdik denotes CH3COCH2COCH3 (Hacac), CH3COCH2COC6H5 (Hbzac), C6H5COCH2COC6H5 (Hdbzm), or (CH3)3CCOCH2COC(CH3)3 (Hdpm). The [In(acac)3] was formed in high yield by the reactions using o-dichlorobenzene, decaline, or DMSO as solvent. The other indium chelate compounds were synthesized by reactions using DMSO as solvent. (author)
Additional details
Publishing Information
- Journal Title
- Bulletin of the Chemical Society of Japan
- Journal Volume
- 67
- Journal Issue
- 9
- Journal Page Range
- p. 2583-2585.
- ISSN
- 0009-2673
- CODEN
- BCSJA8
INIS
- Country of Publication
- Japan
- Country of Input or Organization
- Japan
- INIS RN
- 26039852
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CHEMICAL BONDS; CHEMICAL PREPARATION; INDIUM; INDIUM COMPLEXES; INFRARED SPECTRA; KETONES
- Descriptors DEC
- COMPLEXES; ELEMENTS; METALS; ORGANIC COMPOUNDS; SPECTRA; SYNTHESIS