Published November 22, 2013
| Version v1
Journal article
Surface free energy of a finite system without interfaces at low temperatures
Creators
- 1. Department of Materials Engineering and Chemistry, Czech Technical University, 16629 Prague (Czech Republic)
- 2. Department of Physics, Constantine the Philosopher University, 94974 Nitra (Slovakia)
Description
We derive the specific surface free energy for a rather general system at low temperatures that can be rewritten as a gas of non-interacting contours (polymers). To this end, we use a standard cluster expansion series for the system's partition function. A specific regime of 'weak' boundary conditions is assumed to ensure that no interfaces or large droplets occur in the system. We illustrate the general results, using a simple lattice–gas model.
Availability note (English)
Available from http://dx.doi.org/10.1016/j.physleta.2013.08.032Additional details
Identifiers
- DOI
- 10.1016/j.physleta.2013.08.032;
- PII
- S0375-9601(13)00742-1;
Publishing Information
- Journal Title
- Physics Letters. A
- Journal Volume
- 377
- Journal Issue
- 39
- Journal Page Range
- p. 2718-2722
- ISSN
- 0375-9601
- CODEN
- PYLAAG
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 46009064
- Subject category
- S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS;
- Descriptors DEI
- BOUNDARY CONDITIONS; CLUSTER EXPANSION; DROPLETS; FREE ENERGY; INTERFACES; PARTITION FUNCTIONS; POLYMERS; SPIN; SURFACES
- Descriptors DEC
- ANGULAR MOMENTUM; ENERGY; FUNCTIONS; PARTICLE PROPERTIES; PARTICLES; PHYSICAL PROPERTIES; SERIES EXPANSION; THERMODYNAMIC PROPERTIES
Optional Information
- Copyright
- Copyright (c) 2013 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.