Published November 22, 2013 | Version v1
Journal article

Surface free energy of a finite system without interfaces at low temperatures

  • 1. Department of Materials Engineering and Chemistry, Czech Technical University, 16629 Prague (Czech Republic)
  • 2. Department of Physics, Constantine the Philosopher University, 94974 Nitra (Slovakia)

Description

We derive the specific surface free energy for a rather general system at low temperatures that can be rewritten as a gas of non-interacting contours (polymers). To this end, we use a standard cluster expansion series for the system's partition function. A specific regime of 'weak' boundary conditions is assumed to ensure that no interfaces or large droplets occur in the system. We illustrate the general results, using a simple lattice–gas model.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.physleta.2013.08.032

Additional details

Identifiers

DOI
10.1016/j.physleta.2013.08.032;
PII
S0375-9601(13)00742-1;

Publishing Information

Journal Title
Physics Letters. A
Journal Volume
377
Journal Issue
39
Journal Page Range
p. 2718-2722
ISSN
0375-9601
CODEN
PYLAAG

INIS

Country of Publication
Netherlands
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
46009064
Subject category
S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS;
Descriptors DEI
BOUNDARY CONDITIONS; CLUSTER EXPANSION; DROPLETS; FREE ENERGY; INTERFACES; PARTITION FUNCTIONS; POLYMERS; SPIN; SURFACES
Descriptors DEC
ANGULAR MOMENTUM; ENERGY; FUNCTIONS; PARTICLE PROPERTIES; PARTICLES; PHYSICAL PROPERTIES; SERIES EXPANSION; THERMODYNAMIC PROPERTIES

Optional Information

Copyright
Copyright (c) 2013 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.