Published 2019 | Version v1
Book Metadata-only

Spin-lattice coupling in the (1-x)Pb(Fe2/3W1/3)O3-(1-x)BiFeO3 (x=0.l and 0.4) solid solutions

Creators

  • 1. Department of Physics, Bangalore University, Jnanabharathi Campus, Bangalore - 560 056 (India)
  • 2. New Chemistry Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur P.O., Bangalore-560064 (India)
  • 3. Solid State Physics Division, Bhabha Atomic Research Centre, Mumbai-400085 (India)
  • 4. UGC-DAE-Consortium for Scientific Research, Mumbai Centre, BARC Campus, Mumbai 400085 (India)
  • 5. Department of Physics, School of Engineering, Presidency University, Bangalore-560064 (India)
  • 6. Research Institute of Physics of Southern Federal University, RostOM-on-Don, Stachki avo 194,344090 (Russian Federation)

Description

We report the successful synthesis of (1-x)Pb(Fe2/3W1/3)O3-(1-x)BiFeO3 (PBFW, x=0.1 and 0.4) solid solutions using two-step solid state reaction method. The room temperature XRD and NPD measurement exhibits the Psuedocubic crystal system of space group Pm-3m confirmed through the Rietveld refinement using Fullprof software. Bifurcation of ZFC and FC reveals the strong anisotropic nature in the PBFW. Interestingly, both NPD and magnetic measurement of the PBFW solid solutions exhibits the short range order weak ferromagnetic clusters in the paramagnetic region. The Moessbauer spectroscopy and electron paramagnetic resonance studies exhibits the room temperature magnetically ordered system and show the iron in Fe3+ valence state along with the fraction of Fe2+ ions

Part of:
Proceedings of the forty seventh national seminar on crystallography

Additional details

Publishing Information

Publisher
Bhabha Atomic Research Centre
Imprint Place
Mumbai (India)
Imprint Title
Proceedings of the forty seventh national seminar on crystallography
Imprint Pagination
298 p.
Journal Page Range
p. 152-153

Conference

Title
47. national seminar on crystallography
Acronym
NSC47
Dates
19-22 Jun 2019
Place
Mumbai (India)

INIS

Country of Publication
India
Country of Input or Organization
India
INIS RN
53058901
Subject category
S36: MATERIALS SCIENCE;
Resource subtype / Literary indicator
Conference
Descriptors DEI
CRYSTAL LATTICES; CRYSTALLOGRAPHY; GROUP THEORY; IRON OXIDES; LEAD OXIDES; SPACE GROUPS; SPIN-LATTICE RELAXATION; STRUCTURAL CHEMICAL ANALYSIS; X-RAY DIFFRACTION
Descriptors DEC
CHALCOGENIDES; COHERENT SCATTERING; CRYSTAL STRUCTURE; DIFFRACTION; IRON COMPOUNDS; LEAD COMPOUNDS; MATHEMATICS; OXIDES; OXYGEN COMPOUNDS; RELAXATION; SCATTERING; SYMMETRY GROUPS; TRANSITION ELEMENT COMPOUNDS

Optional Information