Published August 1, 1979 | Version v1
Journal article

Energy dependence of the differential cross sections for simple models of ion-induced dipole capture collisions

  • 1. Chemical Dynamics Laboratory, Department of Chemistry, University of Minnesota, Minneapolis, Minnesota 55455

Description

At low relative kinetic energies, the product angular distributions characteristic of the short range part of a reactive scattering event may become distorted by a long range attractive force. We examine this behavior for several different simple models of direct, short range encounters, each of which is coupled at long range to an attractive potential term proportional to r-4. The long range attraction does not generally lead to symmetric angular distributions for low-energy capture collisions. The anisotropy of the differential cross section which is observed at high energies may be preserved at extremely low kinetic energies, or it may be substantially altered toward either more symmetric or less symmetric distributions. It is even possible for a distribution which is forward-peaked at high energy to become backward-peaked at low energy, and vice versa. These results suggest that caution is warranted when one wishes to interpret a change in the product angular distribution, in going from high kinetic energies to low kinetic energies, as due to a change in the short range reaction mechanism

Additional details

Publishing Information

Journal Title
J. Chem. Phys.
Journal Volume
71
Journal Issue
3
Series
J. Chem. Phys.
Journal Page Range
1128-1133
ISSN
0021-9606

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
11497682
Subject category
S74: ATOMIC AND MOLECULAR PHYSICS;
Descriptors DEI
ANGULAR DISTRIBUTION; ANISOTROPY; DIFFERENTIAL CROSS SECTIONS; ENERGY DEPENDENCE; INTERMOLECULAR FORCES; ION-MOLECULE COLLISIONS; KINETIC ENERGY
Descriptors DEC
COLLISIONS; CROSS SECTIONS; DISTRIBUTION; ENERGY; ION COLLISIONS; MOLECULE COLLISIONS