Published 2009 | Version v1
Journal article

A Soft Alternative to the Dominant {(C5Me5)2U} Motif

  • 1. CEA Saclay, CNRS, IRAMIS, Serv Chim Mol, URA 331, F-91191 Gif Sur Yvette, (France)

Description

In this work, the PNP ligand ([2-(Ph2P)C6H4]2N) has been shown to be flexible, hemi-labile, and capable of stabilizing low- and high-valent uranium species. The bis(PNP) framework is then a valuable alternative to the (C5Me5) ligand set, offering distinct structures and reaction patterns. (O.M.)

Availability note (English)

Available from doi: http://dx.doi.org/10.1002/anie.200900504

Additional details

Identifiers

Publishing Information

Journal Title
Angewandte Chemie (International Edition)
Journal Volume
48
Journal Issue
no.27
Journal Page Range
p. 4898-4899
ISSN
1433-7851

INIS

Country of Publication
Germany
Country of Input or Organization
France
INIS RN
43041724
Subject category
S36: MATERIALS SCIENCE;
Descriptors DEI
ACTINIDES; CRYSTAL STRUCTURE; URANIUM COMPLEXES; VALENCE
Descriptors DEC
ACTINIDE COMPLEXES; COMPLEXES; ELEMENTS; METALS

Optional Information

Notes
11 refs.