Published September 1981
| Version v1
Journal article
Complex formation in molten salts : thermodynamic association constants of cadmium-chloro complexes in molten nitrates
Description
Thermodynamic association constants for the formation of CdCl+ and CdCl2 species in molten KNO2-Ba(NO3)2 (87.6:12.4 mol percent) eutectic in the temperature range 568.2-628.2 K have been determined by the emf method using Pd-PdO-CdO as the indicator electrode. The temperature coefficients of the association constants were predictable from equations based on quasi-lattice model. (author)
Additional details
Publishing Information
- Journal Title
- Proc. Indian Natl. Sci. Acad., Part A
- Journal Volume
- 47
- Journal Issue
- 5
- Series
- Proc. Indian Natl. Sci. Acad., Part A.
- Journal Page Range
- 562-568
- ISSN
- 0370-0046
INIS
- Country of Publication
- India
- Country of Input or Organization
- India
- INIS RN
- 15016848
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- BARIUM NITRATES; CADMIUM COMPLEXES; CHLORINE COMPLEXES; FORMATION FREE ENERGY; HIGH TEMPERATURE; MOLTEN SALTS; POTASSIUM NITRATES
- Descriptors DEC
- ALKALI METAL COMPOUNDS; ALKALINE EARTH METAL COMPOUNDS; BARIUM COMPOUNDS; COMPLEXES; ENERGY; FREE ENERGY; NITRATES; NITROGEN COMPOUNDS; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; POTASSIUM COMPOUNDS; SALTS; THERMODYNAMIC PROPERTIES