Published December 1982 | Version v1
Journal article Metadata-only

Synthesis and study of some properties of bimetallic cobaltocarbonyl derivatives of lanthanides

Creators

  • 1. AN Azerbajdzhanskoj SSR, Baku. Inst. Neorganicheskoj i Fizicheskoj Khimii
  • 2. Nauchno-Issledovatel'skij Fiziko-Khimicheskij Inst., Moscow (USSR)

Description

It has been found that reaction of anhydrous trichlorides of holmium, dysprosium, ytterbium and samarium with cobalt carbonyl and its derivatives NaCo(CO)4, NaCo(CO)3PPh3, Hg[Co(CO)4]2 in the medium of THf at -10-20 deg C results in the formation of previously unknown lanthanides with metal-metal bond. Certain properties of the complexes are studied. All the complexes are characterized by IR spectra and data of element analysis. They do not melt, decompose with decarbonylation, they are easily oxidated by air hydrogen and are easily hydrolyzed

Additional details

Additional titles

Original title (Russian)
Синтез и исследование некоторых свойств биметаллических кобальтокарбонильных производных лантанидов

Publishing Information

Journal Title
Zh. Org. Khim.
Journal Volume
18
Journal Issue
12
Series
Zh. Org. Khim.
Journal Page Range
2482-2485
ISSN
0514-7492

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
14786149
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CARBONYLS; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; CHEMICAL REACTION YIELD; CHLORIDES; COBALT COMPLEXES; DYSPROSIUM COMPLEXES; HOLMIUM COMPLEXES; SAMARIUM COMPLEXES; YTTERBIUM COMPLEXES
Descriptors DEC
CHLORINE COMPOUNDS; COMPLEXES; HALIDES; HALOGEN COMPOUNDS; RARE EARTH COMPLEXES; SYNTHESIS; TRANSITION ELEMENT COMPLEXES

Optional Information

Notes
For English translation see the journal Journal of Organic Chemistry of the USSR (USA).