Computed rotational rainbows from realistic potential energy surfaces
Creators
- 1. Department of Chemistry, University of Rome, Citta Universitaria, 00100 Roma AD, Italy
Description
The quantal IOS approximation in here employed to study interference structures in the rotationally inelastic, state-to-state differential cross sections for polar diatomic targets (LiH, FH, and CO) interacting with He atoms. Quite realistic expressions are used to describe the relevant potential energy surfaces (PES) which were taken from previous works that tested them against accurate experimental findings for total and partial differential cross sections. Specific features like short-range anisotropy and well depth, long-range attractive regions and overall range of action for each potential employed are analyzed and discussed in relation to their influence on rotational rainbows appearance and on the possible observation of cross section extrema in rotational energy distributions
Additional details
Publishing Information
- Journal Title
- J. Chem. Phys.
- Journal Volume
- 83
- Journal Issue
- 3
- Series
- J. Chem. Phys.
- Journal Page Range
- 1049-1058
- ISSN
- 0021-9606
- CODEN
- JCPSA
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 17007593
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- ATOM-MOLECULE COLLISIONS; CARBON MONOXIDE; DIFFERENTIAL CROSS SECTIONS; ENERGY SPECTRA; HELIUM; HYDROFLUORIC ACID; LITHIUM HYDRIDES; ROTATIONAL STATES; SUDDEN APPROXIMATION
- Descriptors DEC
- ALKALI METAL COMPOUNDS; ATOM COLLISIONS; CARBON COMPOUNDS; CARBON OXIDES; CHALCOGENIDES; COLLISIONS; CROSS SECTIONS; ELEMENTS; ENERGY LEVELS; EXCITED STATES; FLUORINE COMPOUNDS; HALOGEN COMPOUNDS; HYDRIDES; HYDROGEN COMPOUNDS; INORGANIC ACIDS; LITHIUM COMPOUNDS; MOLECULE COLLISIONS; NONMETALS; OXIDES; OXYGEN COMPOUNDS; RARE GASES; SPECTRA