Published June 2012 | Version v1
Journal article

Absorption spectrum of deuterated water vapor enriched by 18O between 6000 and 9200 cm-1

  • 1. Laboratory of Theoretical Spectroscopy, V.E. Zuev Institute of Atmospheric Optics, SB RAS, 1, Akademician Zuev Square, 634021 Tomsk (Russian Federation)
  • 2. Hefei National Laboratory for Physical Sciences at Microscale, University of Science and Technology of China, Hefei 230026 (China)

Description

The absorption spectrum of water vapor enriched by deuterium and oxygen-18 is analyzed in the 6000-9200 cm-1 region. The spectrum has been recorded at room temperature with a Bruker IFS 120 h Fourier transform spectrometer. More than 14,000 absorption lines were measured in the recorded spectrum. The vibration-rotation assignments were performed on the basis of previously published experimental energies and of variational calculations. Nine water species (H216O, HD16O, D216O, H218O, HD18O, D218O, H217O, HD17O and D217O) were found to contribute to the observed absorption. More than 3600 lines of 19 vibrational bands of D218O and about 4700 lines of 16 bands of HD18O with J as high as 19 and Ka as high as 11 were assigned. The main part of the HD18O and D218O lines and all lines of HD17O and D217O were observed in the laboratory for the first time. The obtained vibration-rotation energy levels are compared with previous experimental studies and the results of variational calculations.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.jqsrt.2012.02.009

Additional details

Identifiers

DOI
10.1016/j.jqsrt.2012.02.009;
PII
S0022-4073(12)00068-4;

Publishing Information

Journal Title
Journal of Quantitative Spectroscopy and Radiative Transfer
Journal Volume
113
Journal Issue
9
Journal Page Range
p. 653-669
ISSN
0022-4073
CODEN
JQSRAE

Optional Information

Copyright
Copyright (c) 2012 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.