Published 2018 | Version v1
Journal article

Representation of coupled adiabatic potential energy surfaces using neural network based quasi-diabatic Hamiltonians: 1,2 2 A' states of LiFH

  • 1. Johns Hopkins University, Baltimore, MD (United States). Dept. of Chemistry
  • 2. Chinese Academy of Sciences, Dalian (China). Dalian Institute of Chemical Physics, State Key Laboratory of Molecular Reaction Dynamics and Center for Theoretical Computational Chemistry
  • 3. University of New Mexico, Albuquerque, NM (United States). Dept. of Chemistry and Chemical Biology

Description

A general algorithm for determining diabatic representations from adiabatic energies, energy gradients and derivative couplings using neural networks is introduced.

Availability note (English)

Available from https://www.osti.gov/servlets/purl/1594971; https://www.osti.gov/biblio/1594971; DOE Accepted Manuscript full text, or the publishers Best Available Version will be available free of charge after the embargo period

Additional details

Publishing Information

Journal Title
Physical Chemistry Chemical Physics. PCCP (Print)
Journal Volume
21
Journal Issue
26
Journal Page Range
p. 14205-14213
ISSN
1463-9076

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
54043855
Subject category
S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; S97: MATHEMATICAL METHODS AND COMPUTING;
Descriptors DEI
ALGORITHMS; COUPLINGS; HAMILTONIANS; NEURAL NETWORKS; POTENTIAL ENERGY; SURFACES
Descriptors DEC
ENERGY; MATHEMATICAL LOGIC; MATHEMATICAL OPERATORS; QUANTUM OPERATORS

Optional Information

Contract/Grant/Project number
SC0015997
Funding organization
USDOE Office of Science - SC, Basic Energy Sciences (BES) (United States)
Secondary number(s)
OSTIID--1594971