Sorption of fission product radionuclides, 137Cs and 90Sr, by Savannah river site sediments impregnated with colloidal silica

Permeation grouting with colloidal silica gel is a potentially effective means for creating hydraulic barriers to prevent the advective migration of radioactive contaminants in shallow permeable sediments. However, the effectiveness of silica gel grouted barriers in controlling transport of fission product radionuclides through sorption and diffusion is unknown. To resolve this question, static-batch sorption measurements with Cs+ and Sr2+ were conducted at ambient temperature (23 C) and for times up to 96 days on silica gel and on two kaolinitic sediments from the Savannah river site in South Carolina. Sorption experiments on the latter were conducted both in the presence and in the absence of silica gel. Cesium and strontium concentrations were varied between 10-3 to 10-8 M (mol/L) and 10-4 to 10-8 M, respectively. The pH values after one day varied for each experiment and ranged from 3.6 to 6.6. The pH of the solutions were, however, buffered by the sediments and/or silica gel, and changed little over the duration of the experiments. The fraction of both cesium and strontium retained on the solids increased with decreasing radioelement concentration. The sorption data were fitted to the Freundlich isotherm model. (orig.)