Published March 14, 2012 | Version v1
Journal article

Magnetic susceptibility of η-carbide-type molybdenum and tungsten carbides and nitrides

  • 1. Department of Materials Science and Engineering, Kyoto University, Kyoto 606-8501 (Japan)
  • 2. Department of Molecular Science and Technology, Doshisha University, Kyotanabe, Kyoto 610-0394 (Japan)

Description

We synthesized a series of molybdenum and tungsten η-carbide-type compounds and measured their magnetic susceptibility χ. Although the enhancement of χ was observed in several compounds, apparent magnetic order was found only in Fe3W3N (ferromagnetic at 110 K). The broad peak in χ of Fe6W6C is possibly due to antiferromagnetic order. Itinerant electron metamagnetic transitions were observed in Fe3W3C, Fe6W6C, Fe6W6N and Co6W6C. The magnetic enhancement depends on the 3d element in the order Fe > Co > Ni corresponding to DOS at theFermi energy in η-12 systems, whereas no clear trend has been observed in η-6 systems.

Availability note (English)

Available from http://dx.doi.org/10.1088/1742-6596/344/1/012017

Additional details

Publishing Information

Journal Title
Journal of Physics. Conference Series (Online)
Journal Volume
344
Journal Issue
1
Journal Page Range
[4 p.]
ISSN
1742-6596

Conference

Title
From non-living to living systems
Acronym
International and interdisciplinary workshop on novel phenomena in integrated complex sciences
Dates
11-14 Oct 2010
Place
Kyoto (Japan)