Published December 1991 | Version v1
Journal article

Study of paramagnetic Ti and Cr centers in lead zirconate-titanate based solid solutions

  • 1. AN Ukrainskoj SSR, Kiev (Ukraine). Inst. Problem Materialovedeniya

Description

Results of the first observation of Ti3+ and Cr5+ ion ESR spectra in lead zirconate-titanate ceramics PbZr1-xTixO3 (0.39≤x≤0.55) with 0.25% addition of chromium for T=293 K in 3- and 8-mm ranges are presented. It is ascertained that the shape of spectrum is notably linked with x value. Based on the numeric simulation it is shown that the whole collection of experimental results can be explained within the framework of the model in which the ESR spectrum is conditioned by Ti3+ ions as well as by Cr5+ ions in tetragonal and rhombohedral environment

Additional details

Additional titles

Original title (Russian)
Исследование парамагнитных центров титана и хрома в твердых растворах на основе цирконата-титаната свинца

Publishing Information

Journal Title
Fizika Tverdogo Tela
Journal Volume
33
Journal Issue
12
Journal Page Range
p. 3459-3464.
ISSN
0367-3294
CODEN
FTVTAC