Pathways of indium ion transformation consecutive discharge or disproportionation

Alternative mechanisms of indium(3) aquacomplexes discharge were considered on the basis of charge transfer theory in polar solvents and methods of quantum chemistry. Components of solvent reorganization energy, electrostatic parts of regents and products approach energy, as well as activation energy in the course of consecutive stage transfer of electron and for biomolecular reactions of disproportionation, were evaluated. The role of preexpotential coefficients was discussed. It is shown that successive discharge is the most prebable one