Published August 1977
| Version v1
Journal article
Phase composition and phase diagrams of the Ca3(VO4)2 - M3(VO4)2 systems where M - Mg, Zn
Creators
- 1. Ural'skij Zavod Khimicheskikh Reaktivov (USSR)
- 2. AN SSSR, Sverdlovsk. Inst. Khimii
Description
Search of new matrices for luminophores has involved a study of phase composition and state diagrams for the systems containing orthovanadates of the metals of the second group, i.e. Ca3(VO4)2 - Mg3(VO4)2 and Ca3(VO4)2 - Zn3(VO4)2. The existence of compounds with the structure of defect vanadium garnets in the systems has been confirmed. These compounds have been found to melt with decomposition at 1180 +- 5 deg C (Casub(2.5-2.75) Mgsub(2.0-1.75) V3O12) and 905 +- 5 deg C (Casub(2.5-2.75) Znsub(2.0-1.75) V3O12). The garnet structure compounds in these systems display maximum luminescence
Additional details
Additional titles
- Original title (Russian)
- Фазовый состав и диаграммы состояния систем Cа
Publishing Information
- Journal Title
- Izv. Akad. Nauk SSSR, Neorg. Mater.
- Journal Volume
- 13
- Journal Issue
- 8
- Series
- Izv. Akad. Nauk SSSR, Neorg. Mater.
- Journal Page Range
- 1461-1463
INIS
- Country of Publication
- USSR
- Country of Input or Organization
- USSR
- INIS RN
- 9385685
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CALCIUM COMPOUNDS; CHEMICAL COMPOSITION; LUMINESCENCE; MAGNESIUM COMPOUNDS; MELTING POINTS; PHASE DIAGRAMS; PHASE STUDIES; SOLID SOLUTIONS; VANADATES; ZINC COMPOUNDS
- Descriptors DEC
- ALKALINE EARTH METAL COMPOUNDS; DIAGRAMS; DISPERSIONS; HOMOGENEOUS MIXTURES; INFORMATION; MIXTURES; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; SOLUTIONS; THERMODYNAMIC PROPERTIES; TRANSITION ELEMENT COMPOUNDS; TRANSITION TEMPERATURE; VANADIUM COMPOUNDS
Optional Information
- Notes
- For English translation see the journal Inorg. Mater.