Published June 1985 | Version v1
Journal article Metadata-only

A mathematical model for the periodic electrodeposition of multicomponent alloys

Creators

  • 1. Lawrence Berkeley Laboratory, University of California, Berkeley, California

Description

A mathematical model is presented for the electrodeposition of multicomponent alloys by an arbitrarily specified current source. The model takes into consideration transient, convective mass transfer to a rotating disk electrode, Butler-Volmer kinetics, and individual component activities in the electrodeposit. The model can b used to calculate current-potential relationships, ionic concentration profiles, and electrodeposit composition. Results for square-pulse, pulse-reversal, and triangular current waveforms are presented. An analogous model for potential-controlled electrolysis is also discussed

Additional details

Publishing Information

Journal Title
J. Electrochem. Soc.
Journal Volume
132
Journal Issue
6
Series
J. Electrochem. Soc.
Journal Page Range
1298-1307
ISSN
0013-4651
CODEN
JESOA

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
17015754
Subject category
S36: MATERIALS SCIENCE;
Descriptors DEI
ALLOYS; CHEMICAL REACTION KINETICS; ELECTROCHEMISTRY; ELECTRODEPOSITION; ELECTRODES; MASS TRANSFER; MATHEMATICAL MODELS
Descriptors DEC
DEPOSITION; ELECTROLYSIS; KINETICS; REACTION KINETICS; SURFACE COATING