Published March 1, 2010 | Version v1
Journal article Metadata-only

Moessbauer study of oxygen adducts in solid Fe(II) phthalocyanines

Creators

  • 1. Institute of Chemistry, Eoetvoes Lorand University, PO Box 32, 1512 Budapest (Hungary)
  • 2. Department of Chemistry, Drexel University, Philadelphia, PA 19104 (United States)
  • 3. Department of Chemical and Biological Engineering, Ube National College of Technology, Yamaguchi (Japan)
  • 4. Laboratory of Nuclear Chemistry, Chemical Research Center, HAS, PO Box 32, 1512 Budapest (Hungary)
  • 5. Department of Chemistry, University of North Carolina, Asheville, NC 28804 (United States)

Description

Beta iron phthalocyanines (β-FePc) oxygenated at low temperatures were investigated with the help of 57Fe Moessbauer spectroscopy and X-ray diffractometry (XRD). The oxygenation of FePc complex is the key step in the pyrolysis of the flat layered molecules that yields acicular iron carbide particles encaged in uniform carbon shells. Moessbauer spectroscopy revealed that upon oxygenation of β-FePc new species were formed which could be associated with FeIIIPc oxygen adducts in high spin and low spin states. The temperature dependent Moessbauer measurements showed the interconversion of the low spin species into high spin species upon raising the temperature.

Availability note (English)

Available from http://dx.doi.org/10.1088/1742-6596/217/1/012029

Additional details

Identifiers

DOI
10.1088/1742-6596/217/1/012029;

Publishing Information

Journal Title
Journal of Physics. Conference Series (Online)
Journal Volume
217
Journal Issue
1
Journal Page Range
[5 p.]
ISSN
1742-6596

Conference

Title
International conference on the applications of the Moessbauer effect
Acronym
ICAME 2009
Dates
19-24 Jul 2009
Place
Vienna (Austria)

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
42040383
Subject category
S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
Resource subtype / Literary indicator
Conference
Descriptors DEI
ABSORPTION SPECTROSCOPY; ADDUCTS; IRON 57; IRON CARBIDES; MOESSBAUER EFFECT; MOLECULES; PARTICLES; PHTHALOCYANINES; SOLIDS; SPIN; TEMPERATURE DEPENDENCE; X-RAY DIFFRACTION
Descriptors DEC
ANGULAR MOMENTUM; CARBIDES; CARBON COMPOUNDS; COHERENT SCATTERING; DIFFRACTION; DYES; EVEN-ODD NUCLEI; HETEROCYCLIC COMPOUNDS; INTERMEDIATE MASS NUCLEI; IRON COMPOUNDS; IRON ISOTOPES; ISOTOPES; NUCLEI; ORGANIC COMPOUNDS; PARTICLE PROPERTIES; SCATTERING; SPECTROSCOPY; STABLE ISOTOPES; TRANSITION ELEMENT COMPOUNDS