Published March 1982 | Version v1
Journal article

High pressure synthesis of carbonates. 7

  • 1. Hannover Univ. (Germany, F.R.). Inst. fuer Anorganische Chemie

Description

The anhydrous carbonates KLn(CO3)2 with Ln = La to Lu including Y are prepared either from KLn(CO3)2 . xH2O ( Ln = La to Nd) at 350 0C and CO2 pressures to 3000 bar or from K2CO3 and Ln2(C2O4)3 . xH2O (Ln = Sm to Lu including Y) under CO2 pressures to 2000 bar at 500 0C. An orthorhombic Type (Ln = La to Nd) and a monoclinic type are observed. Both types are investigated by IR and X-ray methods. (author)

Additional details

Additional titles

Subtitle (English)
Potassium lanthanoid carbonates
Original title (German)
Hochdrucksynthesen von Carbonaten. 7
Original subtitle (German)
Kalium-Lanthanoid-Carbonate.

Publishing Information

Journal Title
Z. Anorg. Allg. Chem.
Journal Volume
486
Series
Z. Anorg. Allg. Chem.
Journal Page Range
221-228
ISSN
0044-2313