Published November 1988 | Version v1
Journal article

Some observations on the synthesis and HPLC of tris-(acetylacetonato)technetium(III) and (IV) complexes

  • 1. Bhabha Atomic Research Centre, Bombay (India). Radiopharmaceuticals Section

Description

[99Tc(III) (acac)3] was synthesized by published procedure, but recovered by extraction into CH2Cl2. The product was purified by preparative HPLC over a reversed phase column, RP18, using a mobile phase of 1:1 CH3OH:H2O. The cationic complex [99Tc(IV) (acac)3]+ prepared by the oxidation of the purified neutral Tc(III) complex was unstable in methanol/methanol-water medium, being reduced back to the Tc(III) complex. (author) 5 refs.; 3 figs

Additional details

Publishing Information

Journal Title
Journal of Radioanalytical and Nuclear Chemistry
Journal Volume
125
Journal Issue
1
Series
J. Radioanal. Nucl. Chem. ;Articles.
Journal Page Range
97-102
ISSN
0236-5731
CODEN
JRNCD