Published October 2018 | Version v1
Journal article Metadata-only

Polypyrrole entrapped 18-molybdodisulphate anion for the detection of hydrogen peroxide

Creators

  • 1. Interdisciplinary Research Centre in Biomedical Materials (IRCBM), COMSATS University Islamabad, Lahore Campus (Pakistan)
  • 2. Electrochemistry Research Group, Department of Applied Science, Dundalk Institute of Technology, Dublin Road Dundalk, County Louth (Ireland)
  • 3. School of Chemical Sciences, Dublin City University, Glasnevin, Dublin 9 (Ireland)
  • 4. Materials and Surface Science Institute, University of Limerick, Limerick (Ireland)
  • 5. Laboratory of Organic Electronics, Department of Science and Technology, Linköping University, SE-601 74, Norrköping (Sweden)
  • 6. Department of Physics, Chemistry and Biology, Linköping University, SE-581 83, Linköping (Sweden)

Description

Dawson-type 18-molybdodisulphate anion [S2Mo18O62]4-has been immobilized within polypyrrole film by means of electrochemical polymerization. The polymer modified electrodes have been characterized with voltammetry and surface based techniques. The noticeable change in electrochemical properties of [S2Mo18O62]4- has been observed with immobilization, which is favours its electrocatalytic performance. Hydrogen peroxide reduction in neutral pH as a standard system for electrocatalytic properties assessment has been studied on composite film-modified electrodes and showed the sensitivity of 127 mAM−1cm−2. Developed system showed high stabilities towards redox switching and peroxide reduction.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.electacta.2018.08.053

Additional details

Identifiers

DOI
10.1016/j.electacta.2018.08.053;
PII
S0013468618318401;

Publishing Information

Journal Title
Electrochimica Acta
Journal Volume
287
Journal Page Range
p. 78-86
ISSN
0013-4686
CODEN
ELCAAV

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
53030905
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ANIONS; CATALYSIS; DETECTION; ELECTROCHEMISTRY; ELECTRODES; FILMS; HYDROGEN PEROXIDE; ORGANIC POLYMERS; PERFORMANCE; POLYMERIZATION; PYRROLES; SENSITIVITY; STABILITY; SURFACES; VOLTAMETRY
Descriptors DEC
AZOLES; CHARGED PARTICLES; CHEMICAL REACTIONS; CHEMISTRY; HETEROCYCLIC COMPOUNDS; HYDROGEN COMPOUNDS; IONS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; OXYGEN COMPOUNDS; PEROXIDES; POLYMERS

Optional Information

Copyright
Copyright (c) 2018 Published by Elsevier Ltd.