Published June 1975
| Version v1
Journal article
Charge distribution and structure of complexes Mesup(I)GaCl4, Mesup(I)Ga2Cl7, and KAl2Br7 (Mesup(I) = Na+, K+, Rb+, Cs+, Ga+)
Description
35Cl and 69Gasup(III) NQR frequencies are reported for MeGa2sup(III)Cl7 (Me = Na, K, Rb, Gasup(I)) together with the 35Cl NQR frequencies for MeGasup(III)Cl4 (Me = Na, K, Rb, Cs, Gasup(I)), and the 81Br and 79Br NQR frequencies for KAl2Br7. Most of the corresponding 37Cl and 71Gasup(III) resonances in MeGa2Cl7 are reported too. With the exception of RbGaCl4 and CsGaCl4 all NQR investigations were done as a function of the temperature. (orig./HK)
Abstract (German)
Es wurden die 35Cl- und 69Gasup(III)-NQR-Frequenzen von MeGa2sup(III)Cl7 (Me = Na, K, Rb, Gasup(I)), die 35Cl-NQR-Frequenzen von MeGasup(III)Cl4 (Me = Na, K, Rb, Cs, Gasup(I)), sowie die 81Br- und 79Br-NQR-Frequenzen von KAl2Br7 gemessen. Die korrespondierenden 37Cl- und 71Ga-NQR-Frequenzen von MeGa2sup(III)Cl7 wurden soweit als moeglich untersucht. Mit Ausnahme von RbGaCl4 und CsGaCl4 wurden die NQR-Frequenzen als Funktion der Temperatur studiert. (orig./HK)Additional details
Additional titles
- Subtitle (English)
- An NQR investigation ("3"5Cl, "6"9Ga, "8"1Br)
Identifiers
Publishing Information
- Journal Title
- Berichte der Bunsengesellschaft für physikalische Chemie
- Journal Volume
- 79
- Journal Issue
- 6
- Series
- Ber. Bunsenges. Phys. Chem.
- Journal Page Range
- 497-510
- ISSN
- 0005-9021
INIS
- Country of Publication
- Germany
- Country of Input or Organization
- Germany
- INIS RN
- 7236096
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- ALKALI METAL COMPLEXES; BROMINE 79; BROMINE 81; CHEMICAL BONDS; CHLORINE 35; CHLORINE 37; COMPARATIVE EVALUATIONS; CRYSTAL STRUCTURE; DATA; ELECTRIC CHARGES; GALLIUM CHLORIDES; GALLIUM 69; GALLIUM 71; ISOTOPE EFFECTS; NUCLEAR QUADRUPOLE RESONANCE; PHASE TRANSFORMATIONS; QUADRUPOLE MOMENTS; SPECTRA; TEMPERATURE DEPENDENCE
- Descriptors DEC
- BROMINE ISOTOPES; CHLORIDES; CHLORINE COMPOUNDS; CHLORINE ISOTOPES; COMPLEXES; GALLIUM COMPOUNDS; GALLIUM ISOTOPES; HALIDES; HALOGEN COMPOUNDS; INFORMATION; INTERMEDIATE MASS NUCLEI; ISOTOPES; LIGHT NUCLEI; NUCLEI; ODD-EVEN NUCLEI; RADIOISOTOPES; RESONANCE; SECONDS LIVING RADIOISOTOPES; STABLE ISOTOPES
Optional Information
- Notes
- 15 figs.; 11 tabs.; 41 refs.; Updated automatically by Metadata and Full-Text Enrichment Agent