Published September 13, 1978
| Version v1
Journal article
Magnetic field and isotope effects induced by hyperfine interaction in a steady state photochemical experiment
Description
The influence of an external magnetic field on radical reactions is studied in a simple steady-state experiment. This investigates the recombination of a photochemically generated electron donor/acceptor pair (N,N-diethylaniline+-anthracene-) in acetonitrile. As shown by isotopic substitution, the magnetic field dependence of the radical concentrations is due to hyperfine interaction
Additional details
Publishing Information
- Journal Title
- J. Am. Chem. Soc.
- Journal Volume
- 100
- Journal Issue
- 19
- Series
- J. Am. Chem. Soc.
- Journal Page Range
- 5993-5995
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 10440405
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- AMINES; ANTHRACENE; BINDING ENERGY; CHEMICAL REACTION KINETICS; DEUTERIUM; DEUTERIUM COMPOUNDS; INTERACTIONS; ISOTOPE EFFECTS; MAGNETIC FIELDS; NITRILES; ORGANIC SOLVENTS; PHOTOLYSIS; RADICALS
- Descriptors DEC
- AROMATICS; CHEMICAL REACTIONS; CONDENSED AROMATICS; DECOMPOSITION; ENERGY; HYDROCARBONS; HYDROGEN COMPOUNDS; HYDROGEN ISOTOPES; ISOTOPES; KINETICS; LIGHT NUCLEI; NONAQUEOUS SOLVENTS; NUCLEI; ODD-ODD NUCLEI; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; REACTION KINETICS; SOLVENTS; STABLE ISOTOPES