Fabrication of textured REBa2Cu3O7/RE2BaCuO5 (RE = Y, Gd) composites by infiltration and growth of RE2BaCuO5 preforms by liquid phases

A process for the fabrication of high-quality and near-net-shaped superconducting specimens of YBa2Cu3O7 (Y-123) with uniformly distributed fine Y2BaCuO5 (Y-211) is discussed. The process involves the fabrication of 211 preforms by conventional ceramic routes such as uniaxial and isostatic pressing, injection moulding and slip casting, and pressureless infiltration basically from a reservoir containing liquid phases. A compact of 123 or 123 rich in liquid phases(s), acting as a source of liquid phases, is placed in contact with the 211 preform, and heated above the peritectic temperature of 123. The liquid from the source compact infiltrates the 211 filler and the peritectic reaction occurring between the preform material (211) and the matrix (liquid phases) during slow cooling from the peritectic temperature results in the growth of 123 with uniformly distributed fine 211 particles. We have also demonstrated that the present process can be extended to the fabrication of other rare earth (RE) superconductors where a solid solution of the kind RE1+xBa1-xCu3O7 occurs due to comparable size of the RE and Ba atoms, by choosing the RE = Gd system as an example. Herein the advantages and bounds of the process are reviewed; the effect of various cooling rates on the growth kinetics of 123 and the resulting macro- and microstructures are discussed. Fabrication of composites containing fine and very uniformly distributed Ag is also demonstrated by the process. Comparisons are made between the characteristics of the samples produced in the present process and the existing melt texturing process. The utility of the process is demonstrated by the fabrication of a three-dimensional component - a hollow cylinder. (author)