Recharge and residence times of groundwater in hyper arid areas: The confined aquifer of Calama, Loa River Basin, Atacama Desert, Chile

Highlights: • The study of the river-aquifer relationship in hyper arid zones is essential for the management of water resources • The low radiocarbon concentrations in the Loa river waters are transferred to the aquifer system of the Calama basin • The confined aquifer is mostly recharged by Loa River water infiltration • DIC radiocarbon ages indicate a groundwater travel time between 1500 and 4000 years in the Calama basin confined aquifer. Groundwater recharge in hyper arid areas often depends on surface water infiltration and diffuse recharge of highly evaporated precipitation only contribute under favorable conditions. This happens in the Calama basin two-aquifer system, in the Central Andean area of northern Chile. A conceptual model of the groundwater system and its relationship with the Loa River is defined. We focus on the confined aquifer of the Calama basin, combining hydrodynamic, hydrogeochemical and isotopic methods. Radiocarbon (¹⁴C) activity data of dissolved inorganic carbon (DIC), in conjunction with chemical data, are applied to evaluate groundwater residence time within the confined aquifer. The Loa River recharges the Calama basin aquifers in its northeastern part, with water that has chemical and isotopic characteristics inherited from the arid environment and volcanic rocks in its upper basin. In the central and northeastern part of the confined aquifer, minor variations in chloride concentration suggest that the deep aquifer is well confined. The δ¹⁸O and δ²H values in groundwater of the confined aquifer show an increasing isotopic fractionation from the recharge area (around −10‰ δ¹⁸O) to those in the discharge area (between −8.5‰ and −8‰) in the southwestern part of the aquifer. The ¹⁴C activity continuously decreases down flow from the recharge by the Loa River. Adjusted DIC radiocarbon ages indicate a groundwater travel time between 1500 and 4000 years in the confined aquifer of Calama. Despite the limitations and uncertainties of radiocarbon in DIC to estimate groundwater transit times for the confined aquifer and considering complementary chemical and isotopic constraints, the DIC ¹⁴C provides acceptable values. The approach may be applicable in other confined aquifers in hyper-arid climates in which the formation of aquifer systems linked to river damming by geological action took place. This information is needed for sound management of the scarce groundwater resources.